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Unlike PZT-Based Ferroelectric Memories, These Devices Are Fully Compatible With CMOS Processes, Scalable to Advanced Nodes and Lead-Free
SAN FRANCISCO – Dec. 15, 2021 – CEA-Leti has reported the world's-first demonstration of 16-kbit ferroelectric random-access memory (FeRAM) arrays at the 130nm node that advances this energy-saving technology closer to commercialization. The breakthrough includes back-end-of-line (BEOL) integration of TiN/HfO2:Si/TiN ferroelectric capacitors as small as 0.16 µm², and solder reflow compatibility for the first time for this type of memory.
The results were reported in a paper, "16kbit HfO2:Si-based 1T-1C FeRAM Arrays Demonstrating High Performance Operation and Solder Reflow Compatibility", at IEDM 2021.
"This ultralow-power, fast, high-endurance, CMOS-compatible BEOL FeRAM memory uses a new HfO2-based ferroelectric material that also is more environmentally friendly than PZT," said Laurent Grenouillet, an author of the paper. "This demonstration will pave the way toward embedded non-volatile memories at more advanced technology nodes."
The highly versatile technology is expected to be interesting for embedded applications such as Internet of Things (IoT) devices and wearables.
Since ferroelectricity was first discovered in HfO2-based films a decade ago, much of the ferroelectric memory research that has been published has focused on the materials themselves or on large-area, single-device performance.
In the CEA-Leti work, the team observed zero bit failure at the array level, with the memory window fully open down to 2.5 V programming voltage, and ultrafast switching speed down to four nanoseconds. Array-level endurance was also promising at up to 10 million cycles, as was array-level data retention at 125 °C for 104s (three hours).
"HfO2-based ferroelectric capacitors change the paradigm of FeRAM," Grenouillet added. "Unlike PZT-based ferroelectric memories, HfO2-based FeRAM are fully CMOS compatible, and scalable to advanced nodes, in part because HfO2-based ferroelectric films are very thin, typically 10nm thick. They are also lead-free, which is less detrimental to the environment."
CEA-Leti's multidisciplinary know-how spanning materials development, characterization, simulation and integration was instrumental in the design and fabrication of the demonstrator arrays, which also showed power consumption more than 100 times lower than conventional Flash memories.
The work was supported by the EU's 3eFERRO Consortium project that was designed to produce new ferroelectric material Hf(Zr)O2 that makes FeRAM a competitive NVM candidate for IoT applications
CEA is a French government-funded technological research organisation in four main areas: low-carbon energies, defense and security, information technologies and health technologies. A prominent player in the European Research Area, it is involved in setting up collaborative projects with many partners around the world.